Synthesis of Hydroxypropyl Guar Gum by Phase Transfer Catalysis

HGG (Hydroxypropyl guar gum) was synthesized by phase transfer catalysis for the first time. The effects of alkalinity, phase transfer catalyst, etherification, pH value, temperature,reaction time and stirring speed were investigated. An optimal synthetic reaction technology was established, namely, dose of guar gum is 100 g, propylene oxide 40-50 g, HTAC (hexadecyl trimethyl ammonium chloride ) 1.3-1.7 g, pH value 10-10.5, temperature 45-50℃, and reaction time 3-4 hours. The result shows that the improved HGG has high viscosity. Its dissolution speed, content of insoluble residue, colloid light transparency and stability are apparently superior to guar flour.

作 者： Rong Chun XIONG Ming Zhu CHANG Jian Ming CHEN Nan ZHOU Gang WEI   作者單位： Beijing University of Chemical Technology, Beijing 100029  刊 名： 中國(guó)化學(xué)快報(bào)（英文版）  ISTIC SCI 英文刊名： CHINESE CHEMICAL LETTERS  年，卷(期)： 2005 16(4)  分類號(hào)：   關(guān)鍵詞： Guar gum   hydroxypropyl guar gum   chemical modification   phase transfer catalysis  

【Synthesis of Hydroxypropyl Guar Gum 】相關(guān)文章：

Synthesis of 4-Aminosalicylglycine04-26

Study on synthesis of polylactide from kitchen garbage04-25

Synthesis of nanosize MnO2 and its performence04-27

Synthesis and Crystal Structure of Binuclear Copper(Ⅱ)Complex Containing (Dimethylaminomethyl)ferrocene04-27

Enhanced activity of yqhD oxidoreductase in synthesis of 1,3-propanediol by error-prone PCR04-26

Synthesis and Crystal Structure of 1,4-Bis(2-hydroxymethylphenyl)-1,4-dioxabutane04-27

Synthesis and Crystal Structure of N,N-Diphenyl-3,6-diethyl-1,4-dihydro-s-tetrazine-1,4-dicarbonamide04-26

Synthesis and Crystal Structure of 1-(Trifluoromethyl)-1-(propioloyl)-(E)-3-oxo-(2-thienyl)-(2-naphthylamine)04-26

Synthesis and Structure of [Cu2(μ-NO2)(aepy)4](ClO4)3 (aepy = 2-(2-Aminoethyl)pyridine)04-27